本人专业是材料，具体涉及介孔。因此对介孔材料从合成表征，到形成机理，到性能应用都很感兴趣。但是无奈自己资质愚钝，又不奋发，因而学识寡漏。本人发起这个主题，只能算是抛砖，希望引来各位介孔方面的能人施玉。
     而从事介孔的，或是对介孔有兴趣的学术朋友汇集于此，共享资源，畅谈介孔，可谓快哉。

   我还是以介孔方面出现的文献为内容，介绍介孔制备方面的发展：  
1.介孔材料的诞生－－1992年MS41系列分子筛(典型的是MCM-41,MCM-48,MCM-50)的合成（严格来讲，应该是1991年日本人合成出来）：
Nature. 1992, 359, 710-712（J. S. Beck）
J Am Chem Soc. 1992, 114: 10834-10843（J. S. Beck）
Science. 1993, 261: 1299-1303(霍启升）
2.介孔材料制备的另一里程碑－－1998年赵东元合成了SBA-15
Science. 1998, 279: 548-552（赵东元）
J. Am. Chem. Soc. 1998, 120, 6024-6036 （赵东元）
3.通过硬模板法合成炭基介孔材料，也是一大重要成绩－－1999年由韩国人刘龙完成：
J Am Chem Soc. 2002, 124: 1156-1157( Ryoo R.)

[ Last edited by 604gq on 2008-3-26 at 15:02 ]

密切关注中

介孔相关的几个牛人的课题组：

http://www.mrl.ucsb.edu/mrl/info/publications/ （G. D. Stucky)
http://www.cem.msu.edu/~pinnweb/ （Thomas J. Pinnavaia）
http://www.chem.toronto.edu/staff/GAO/flashed/menu.htm （Ozin's group）
http://homepage.fudan.edu.cn/~dyzhao/ （赵东元）
http://rryoo.kaist.ac.kr/pub.html (韩国刘龙 （R. Ryoo）)
http://cheed.nus.edu.sg/~chezxs/Zhao/publication.htm（新加坡赵修松 Xiusong Zhao)
http://www.ucm.es/info/inorg/investiga/publicaciones/2001/2001.htm (西班牙M. Vallet-Regi 首先把介孔材料应用到药物缓释）
因为以前不小心把自己的收藏夹弄没了，所以有还有几个课题组现在没有了链接，但是其课题负责人还是记得：
台湾的牟中原和他的弟子林弘平
上海硅所的施剑林
吉林大学的肖丰收和裘式伦
大化所的包信和（涉及得不多）

[ Last edited by 604gq on 2007-4-26 at 17:36 ]

支持！
;)

推荐几篇介孔材料重要的综述：

Chem. Mater. 1996, 8, 1147-1160 Surfactant Control of Phases in the Synthesis of Mesoporous Silica-Based Materials(Stucky和霍启升 表面活性剂的堆积参数和结构的关系）

Chem. Rev. 1997, 97, 2373-2419   From Microporous to Mesoporous Molecular Sieve Materials and Their Use in Catalysis（主要介绍介孔作催化载体的应用）

Chem. Rev. 2006, 106, 3790-3812 Advances in the Synthesis and Catalytic Applications of Organosulfonic-Functionalized Mesostructured Materials（有机官能化介孔的合成及在催化中的应用）

Acc. Chem. Res. 2002, 35, 927-935　Structural and Morphological　Control of Cationic　Surfactant-Templated　Mesoporous Silica（牟中原 具体谈论介孔形貌的形成）　

Angew. Chem. Int. Ed. 2006, 45, 3216–3251 Silica-Based Mesoporous Organic-Inorganic Hybrid Materials（Frank Hoffmann 所著，非常好）

Acc.Chem.Res.2005, 38,305-312 Past, Present, and Future of Periodic Mesoporous Organosilicas-The PMOs（O'zin 重点介绍周期性介孔）

NATURE  2002  417 813  Ordered porous materials for emergeing application
（大牛Davis所著）

Chem. Mater. 1999, 11, 2633-2656  Tailored Porous Materials(Thomas J.)

介孔分子筛的应用：

介孔分子筛吸附氨基酸：
Carbon 44 (2006) 530–536 Adsorption of L-histidine over mesoporous carbon molecular sieves(印度人 A. Vinu）

Separation and Purification Technology 48 (2006) 197–201 Amino acid adsorption onto mesoporous silica molecular sieves （首篇）

介孔分子筛吸附蛋白质（酶）
Journal of Molecular Catalysis B－ Enzymatic  2（1996） 115－ 126 Enzyme immobilization in MCM-4 1 molecular sieve（首篇）

J. Am. Chem. Soc. 1999, 121, 9897-9898 Mesoporous Silicate Sequestration and Release of Proteins（stucky)

J. AM. CHEM. SOC. 2004, 126, 12224-12225 Protein Encapsulation in Mesoporous Silicate-The Effects of Confinement on Protein Stability, Hydration, and Volumetric Properties

J. Phys. Chem. B 2003, 107, 8297-8299 Adsorption of Cytochrome C on New Mesoporous Carbon Molecular Sieves(Vinu, A)

介孔分子筛负载催化剂
J. Phys. Chem. B 2006, 110, 15212-15217 Fabrication and characterization of mesoporous Co3O4 core-mesoporous silica shell nanocomposites（典型的core－shell结构）

CHEM. COMMUN., 2003, 1522–1523 Ultra-thin porous silica coated silver–platinum alloy nano-particle as a new catalyst precursor

Applied Catalysis A General 308 (2006) 19–30 Carbon oxide hydrogenation over silica-supported iron-based catalysts Influence of the preparation route

Chem. Commun., 2005, 348–350 Metallic Ni nanoparticles confined in hexagonally ordered mesoporous silica material

介孔分子筛在药物可控释放方面的应用
Chem. Mater. 2001, 13, 308-311    A New Property of MCM-41, Drug Delivery System（Vallet-Regi 首篇）

Nature 2003, 421, 350 – 353　Photocontrolled reversible release　of guest molecules from coumarinmodified　modified　mesoporous silica（第一次只能化）

J. AM. CHEM. SOC. 2005, 127, 8916-8917 Fabrication of Uniform Magnetic Nanocomposite Spheres with a Magnetic Core-Mesoporous Silica Shell Structure-support（施剑林 所谓的“药物分子运输车”）

Angew. Chem. Int. Ed. 2005, 44, 5038 –5044 Stimuli-Responsive Controlled-Release Delivery System Based on Mesoporous Silica Nanorods Capped with Magnetic Nanoparticles（Victor S.-Y. Lin* 在智能介孔药物释放方面是贡献巨大）

介孔分子筛吸附废水阳离子
Chemosphere 59 (2005) 779–786  Heavy metals removal from electroplating wastewater by aminopropyl-Si MCM-41

Environ. Sci. Technol.2000, 34,4822-4827 Surfactant-Templated Mesoporous Silicate Materials as Sorbents for Organic Pollutants in Water

Ind. Eng. Chem. Res. 2004, 43, 1478-1484 Highly Selective Adsorption of Pt2+ and Pd2+ Using Thiol-Functionalized Mesoporous Silica

介孔分子筛在色谱中的应用
Chem. Commun., 2002, 752 - 753　Biomolecule separation using large pore mesoporous SBA-15 as a substrate in high performance liquid chromatography

Electrophoresis 2006,27,742–748 Large-pore　mesoporous SBA-15　silica　particles with submicrometer　size as　stationary phases for　high-speed CEC　seperation

介孔分子筛作为硬模板
Adv. Mater. 2001, 13,　677-681　Ordered Mesoporous Carbons（Ryong Ryoo）

Microporous and Mesoporous Materials 63 (2003) 1–9 Synthesis and characterization of spherical carbon and polymer capsules with hollow macroporous core and mesoporous shell structures

介孔分子筛复合材料（实现光学性能，比如掺入二氧化钛，量子点）
J. Phys. Chem. B 2005, 109, 12309-12315 Synthesis and Characterization of Nano titania Particles Embedded in Mesoporous Silica with Both High Photocatalytic Activity and Adsorption Capability

Chem. Mater. 2005, 17, 1269-1271 Preparation of Mesoporous Titania Thin Films with Remarkably High Thermal Stability

J. AM. CHEM. SOC. 2006, 128, 688-689　Magnetic Fluorescent Delivery Vehicle Using Uniform Mesoporous Silica　Spheres Embedded with Monodisperse Magnetic and Semiconductor　Nanocrystals　　

介孔分子筛薄膜

[ Last edited by 604gq on 2007-4-27 at 20:36 ]

:D
呵呵，只是个微球！
估计10微米以上！正在优化条件！

[ Last edited by zjx121610 on 2007-4-26 at 21:52 ]

形态不错啊`:P

Mesoporous templated silicates: an overview of their synthesis, catalytic activation and evaluation of the stability.

Adv Colloid Interface Sci. 2003 Apr 25;103(2):121-47.
color]
Linssen T, Cassiers K, Cool P, Vansant EF.
Laboratory of Adsorption and Catalysis, Department of Chemistry, Universiteitsplein 1, B-2610 Wilrijk, Belgium. thierry.linssen#ua.ac.be

The most recent developments in the formation of new mesoporous templated zeolitic materials, characterized by surfaces of more than 1000 m(2)/g, are discussed in this paper. By adapting the synthesis parameters, such as type of silicium source, type of template, pH, temperature, em leader different materials can be synthesized with varying porosity and crystallinity. Besides the synthesis, much attention is focused on the activation of their surfaces by incorporation methods or deposition processes towards catalytic applications. Finally, the stability of the different materials, one of the critical parameters to potential industrial applications, is compared and evaluated.

[ Last edited by zhaokelun1975 on 2007-4-27 at 00:46 ]