1965年,ANALYTICAL CHEMISTRY 上一篇文章
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The theory of cyclic voltammetry has been extended to include electron
transfer reactions which are described by the electrochernical absolute rate
equation. Results of theoretical calculations made it possible to use cyclic
voltammetry to measure standard rate constants for electron transfer. Thus,
a system which appears reversible at one frequency may be made to
exhibit kinetic behavior at higher frequencies, as indicated by increased
separation of cathodic and anodic peak potentials. The standard rate
constant for electron transfer is determined from this peak potential
separation and frequency. The method provides an extremely rapid
and simple way to evaluate electrode kinetics. The reduction of cadmium
is used as an illustration.
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[ Last edited by zzgyb on 2007-12-13 at 13:08 ]